PRODUCT AND COMPANY IDENTIFICATION
Product Name
:
Sulfuric Acid
No
:
GSR - SDS 002
Company name
:
PT. Smelting, Gresik Smelter and Refinery
Address
:
Desa Roomo, Kecamatan Manyar PO. Box 555 Gresik 61151 Jawa Timur - Indonesia
Telephone Number
:
62-31-397-6458/59
Fax Number
:
62-31-397-6460
COMPOSITION /INFORMATION ON INGREDIENTS
Chemical Formula
:
H2SO4
SNI No
:
0030:2011
PT Smelting ISO Document
:
AP-SP-300-01-01
| Element | Specification |
|---|---|
| H2SO4 | ≥ 98.2 % |
| Turbidity | ≤ 60 NTU |
| Ignition Residue | ≤ 0.02% b/b ≈ 200 ppm |
| Chlorine (Cl) | ≤ 5 ppm |
| Iron (Fe) | ≤ 40 ppm |
| Lead (Pb) | ≤ 9 ppm |
| Arsenic (As) | ≤ 0.2 ppm |
| Copper (Cu) | ≤ 1 ppm |
| Selenium (Se) | ≤ 0.5 ppm |
| Zinc (Zn) | ≤ 2 ppm |
HAZARD IDENTIFICATION
Emergency Overview :
Sulfuric Acid is clear, colorless, odorless, dense, oily liquid. It can decompose at high temperatures forming toxic gases, such as sulfur oxides. If it contacts with combustible materials may cause fire. Sulfuric acid is highly reactive. Contact with many organic and inorganic chemicals may cause fire or explosion. If it contacts with metals liberates flammable hydrogen gas and if it reacts violently with water it will be very toxic. It may cause fatality if inhaled or swallowed. It is corrosive to the eyes, skin and respiratory tract. It may cause blindness and permanent scarring. It causes lung injury (effects may be delayed). Strong inorganic acid mists containing sulfuric acid are carcinogenic.
Potential Health Effects
Eyes
:
Causes severe eye burns. May cause irreversible eye injury.
Skin
:
Causes skin burns. Stimulates dermatitis with prolonged use.
Ingestion
:
May cause severe and permanent damage to the digestive tract. Causes burns in mouth, pharynx and gastrointestinal tract. Nausea, Vomiting, Abdominal pain. Corrosive and toxic.
Inhalation
:
Harmful if inhaled. May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. May cause respiratory inflammation. Destructive to tissues of mucous membranes. Headache, May cause delayed lung injury. Vomiting. Nausea. Pulmonary edema. Corrosive and toxic
Chronic Effects
:
Prolonged or repeated inhalation may cause nosebleeds, nasal congestion, erosion of the teeth, perforation of the nasal septum, chest pain and bronchitis. Prolonged or repeated eye contact may cause conjunctivities. May cause death. Corrosive to body tissues. To the best of our knowledge the chronic toxicity of this substance has not been fully investigated.
FIRST AID MEASURES
Eye Contact
:
Immediately flush eyes and skin with copious amounts of water for at least 15 minutes, holding lids apart to ensure flushing of the entire surface. Do not allow victim to rub eyes or keep eyes closed. Get medical aid immediately.
Skin Contact
:
Get medical aid immediately. Immediately flush skin with copious quantities of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Inhalation
:
Get medical aid immediately. Remove the patient from exposure to fresh air immediately. Administer approved oxygen supply if breathing is difficult. Administer artificial respiration or CPR if breathing has ceased. Call a physician.
Ingestion
:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Consult a physician immediately. Never give anything by mouth to an unconscious person.
FIRE FIGHTING MEASURES
Fire and Explosion Hazards
:
Oxidizing material – contributes to combustion of other materials. Reacts violently with water and organic materials with evolution of heat. Emits toxic and corrosive fumes under fire conditions.
Flashpoint
:
Not available
Flammable limit
:
Not available
Autoignition Temperature
:
Not available
Extinguishing Media
:
Use extinguishing media most appropriate for the surrounding fire. Carbon dioxide. Dry chemical power. Do not use water.
Fire Fighting
:
Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Contact with water can cause violent liberation of heat and splattering of the material.
ACCIDENTAL RELEASE MEASURES
Procedure for Clean Up
Evacuate. Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. Cover with soda ash or lime. Place in a suitable container and mark for disposal. Use non-sparking tools. Ventilate area and wash spill site after material pick-up is complete.
Personal Precaution
Use proper personal protective equipment such as eyeglasses or chemical safety goggles, appropriate protective neoprene or polyethylene gloves, and respirator.
Environmental Precaution
Cover with sand, dry lime or soda ash, and place in a closed container for disposal.
HANDLING AND STORAGE
Handling Precaution
Wash thoroughly after handling. Remove contaminated clothing and wash before re-use. Use with adequate ventilation. Do not get in eyes, on skin or on clothing.
Storage Precaution
Store the material in a cool, dry, well-ventilated area, protected from direct sunlight and rainfall. Storage should be equipped with waterproof floor and lightning protection system. Do not store in a damp atmosphere. Store the material in a cool place away from heated areas, sparks and flame. Do not store near alkaline, combustible, organic and flammable material/ substances. Keep container closed when not in use. Do not add any other material to the container. Do not get in eyes, on skin or on clothing. Do not allow smoking and food consumption while handling. Wash well after use. In accordance with preventing of pollution, any spillage should not be discharge into the environment. Symbol and emergency response equipments should be provided in accordance with applicable regulations.
Work/Hygienic Practices
Always practice good personal hygiene. Refrain from eating, drinking, or smoking in work areas. Thoroughly wash hands before eating, drinking, or smoking in appropriate, designated areas.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye/Face Protection
:
Wear appropriate protective eyeglasses or chemical safety goggles.
Skin Protection
:
Wear appropriate protective neoprene or polyethylene gloves to prevent skin exposure.
Body Protection
:
Wear appropriate protective clothing such as Apron, and rubber boots to prevent skin exposure.
Respiration
:
Use respirators and components tested and approved under appropriate government standards.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance
:
Clear and nearly white
Odour
:
None
Physical State
:
Liquid
Temperature
:
≤ 38°C
Vapour Density
:
Not Applicable
Boiling Point/Range
:
Not Applicable
Melting Point/Range
:
50.6°F
Solubility
:
Soluble in water and ethanol.
STABILITY AND REACTIVITY
Stability
The product is stable under normal temperatures and pressures
Condition to Avoid
Incompatible materials, contact with water, metals, excess heat, combustible materials, organic materials, oxidizers, amines, bases.
Incompatible Materials
Acetic Anhydride, Acetone Cyanhydrin, Acetone + Nitric Acid, Acetone + Potassium Dichromate, Acetonitrile + Sulphur Trioxide, Acrolein, Acrylonitrile, Alcohols + Hydrogen Peroxide, Allyl Alcohol, Allyl and Aldehyde compounds, Allyl Chloride, 2-Aminoethanol, Ammonium Hydroxide Ammonium Iron (III) sulfate dodecahydrate, Ammonium Triperchromate, Aniline + Glycerol + Nitrobenzene, Benzyl Alcohol, Bromates + Metals, tert-Butyl-m-xylene + Nitric Acid, 1-Chloro-2,3-epoxypropane, Bromine Pentafluoride, n-Butyraldehyde, Cesium Acetylene Carbide, 4-Chloronitrobenzene + sulphur trioxide, Copper, Dichloromethane + Ethanol + Nitrate or Nitrite, 2-Cyano-4-nitrobenzenediazonium hydrogen sulphate, 2-Cyano-2-propanol, Chlorine Trifluoride, Chlorosulfonic Acid (Cyanides), Cycolpentadiene, Cyclopentanone oxime, 1,3-Diazidobenzene, Diethylamine, Cuprous Nitride, Diisobutylene, Ephchlorohydrin, Ethylene Cyanohydrin, Ethylene Diamine, Ethylene Glycol, Dimethoxydinitroanthraquinone, 4-Dimethylaminobenzaldehyde, 2,5-Dinitro-3-Methylbenzoic acid + Sodium Azide, 1,5-Dinitronaphthalene + Sulfur, Ethoxylated nonylphenol, Fulminates, Halides, Hexalithium disilicide, Ethylenimine, Other Acids, Iodine Heptafluoride, Metals, Isoprene, Hydrofluoric acid, Hydrogen peroxide, Metal acetylides or carbides, Metal Chlorates, Metal Perchlorates, 4-Methuylpyridine, Nitramide, Nitric Acid + Organic materials, Nitric Acid + Toluene, Nitrites, Nitroaryl bases and derivatives, Nitrobenzene, 3-Nitrobenzenesulfonic Acid, Nitromethane, N-Nitromethylamine, 4-Nitrotoluene, Permanganates, Phosphorus, Phosphorus (III) Oxide, Poly(silylene), Mercuric Nitride, Mesityl Oxide, P-Nitrotoluene, Pentasilver Trihydroxydiaminophosphate, Perchlorates, Permanganates + Benzene, Phosphorus Isocyanate, Picrates, Potassium t-Butoxide, Potassium, 3-Propynol, Potassium Chlorate, beta-Propiolactone, Propylene Oxide, Pyridine, Ruybidium Acetylene Carbide and Sodium, Silver Pemanganates, Silver Peroxochromate, Sodium, Sodium Carbonate, Sodium Tetrahydroborate, Sodium Thiocyanate, Sucrose, Tetramethylbenzenes, 1,2,4,5-Tetrazine, Thallium (I) azidodithiocarbonate, 1,3,5-Trinitrosohexahydro-1,3,5-triazine, Water, and Zinc Iodide. Carbonates, sulfides, sulphites, carbides, chlorates.
Hazardous Decomposition
Oxides of Sulphur.
Hazardous Polymerization
Has not been reported.
TOXICOLOGICAL INFORMATION
Teratogenicity
:
No Information Available.
Reproductive
:
No Information Available.
Mutagenicity
:
No Information Available
Neurotoxicity
:
No Information Available
ECOLOGICAL INFORMATION
Sulphuricacid is harmful to aquatic life in very low concentrations. It may be dangerous if it enters water intakes. The aquatic toxicity for bluegill in fresh water was 24.5 ppm/24 hr, which was lethal.
DISPOSAL CONSIDERATIONS
Sulfuric acid may be placed in sealed container or absorbed in vermiculite, dry sand, earth, or a similar material. It may also be diluted and neutralized. Be sure to consult with local or regional authorities (waste regulators) prior to any disposal. Waste must be disposed of in accordance with federal, state and local environmental control regulations.
TRANSPORT INFORMATION
Facilities for transportation purposes using acid-resistant materials.
REGULATORY INFORMATION
Originally prepared by PT Smelting , April 2020
PT Smelting has prepared this material safety data sheet in order to provide product information which will assist our customers in complying government standard.